Oak Ridge National Laboratory Designs and Tests All Solid Lithium-Sulfur Battery with 4 Times the Energy Density of Lithium-Ion
Researchers at Oak Ridge National Laboratory (ORNL) have successfully demonstrated that lithium-sulfur battery technology can indeed outdo lithium-ion on several fronts.
At ORNL, researchers “designed and tested an all-solid lithium-sulfur battery with approximately four times the energy density of conventional lithium-ion technologies,” says Green Car Congress, who further adds that “The ORNL battery design also addresses flammability concerns experienced by other chemistries.”
We all know that, in theory, lithium-sulfur is an energy-dense beast. Theoretically, lithium-sulfur has the potential to be four times as energy dense as today’s lithium-ion batteries, but that’s all in theory and, until a working example is demonstrated, we’re all left dreaming.
However, the steps made by ORNL show true promise. Remember, there have been some breakthroughs related to extended the longevity of lithium-sulfur, but the problem with the liquid electrolyte breaking down the battery over time still remains with this chemistry.
Not anymore, says ORNL.
ORNL’s lithium-sulfur battery does away with the conventional liquid electrolyte in favor of solid electrolyte material. As Green Car Congress says:
“The ORNL team overcame these barriers by first synthesizing a new class of sulfur-rich materials—lithium polysulfidophosphates (LPSPs)—that conduct ions as well as the lithium metal oxides conventionally used in the battery’s cathode.”
“LPSPs have ionic conductivities of 3.0×10−5 S cm−1 at 25 °C, which is 8 orders of magnitude higher than that of Li2S (lithium sulfide). The high lithium ion conductivity imparts excellent cycling performance, the researchers noted.”
“The researchers then combined the new sulfur-rich cathode and a lithium anode with a solid electrolyte material, also developed at ORNL, to create an energy-dense, all-solid battery.”
And here’s an excerpt from ORNL’s research paper, which was published in Angewandte Chemie International Edition:
“Our approach is a complete change from the current battery concept of two electrodes joined by a liquid electrolyte, which has been used over the last 150 to 200 years. This game-changing shift from liquid to solid electrolytes eliminates the problem of sulfur dissolution and enables us to deliver on the promise of lithium-sulfur batteries. Our battery design has real potential to reduce cost, increase energy density and improve safety compared with existing lithium-ion technologies.”
Now for some of the gritty technical details, presented by Green Car Congress:
“The new ionically-conductive cathode enabled the ORNL battery to maintain a capacity of 1,200 mAh/ g after 300 charge-discharge cycles at 60 °C. By comparison, a conventional lithium-ion battery cathode has an average capacity between 140-170 mAh/g. Because lithium-sulfur batteries deliver about half the voltage of lithium-ion versions, this eight-fold increase in capacity demonstrated in the ORNL battery cathode translates into four times the gravimetric energy density of lithium-ion technologies.”
Most importantly, though, is that the inclusive of solid electrolyte materials makes the battery inherently safer than ones that use a liquid.
ORNL’s potential breakthrough lithium-sulfur battery is still in the demonstration/development phase. Commercialization is tentatively set for…quickly. Actually, there’s no set timeline for commercialization, but a patent is at least pending for ORNL’s design.
Source: Green Car Congress